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Fiorenza Gianì Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Giuseppe Pandini Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Nunzio Massimo Scalisi Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Paolo Vigneri Medical Oncology and Center of Experimental Oncology and Hematology, Department of Clinical and Experimental Medicine, University of Catania, A.O.U Policlinico Vittorio Emanuele, Catania, Italy

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Carmine Fazzari Humanitas, Catania Oncology Center, Catania, Italy

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Pasqualino Malandrino Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Marco Russo Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Romilda Masucci Surgical Oncology, Garibaldi-Nesima Medical Center, Catania, Italy

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Antonino Belfiore Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Gwabriella Pellegriti Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy

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Riccardo Vigneri Endocrinology, Department of Clinical and Experimental Medicine, University of Catania, Garibaldi-Nesima Medical Center, Catania, Italy
IC Crystallography Institute, National Research Council, CNR, Catania, Italy

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concentration of these elements in the urines and hair of residents ( Varrica et al. 2014 , Malandrino et al. 2016 ). In particular, four elements (boron, molybdenum, palladium and tungsten) exceed the urine reference values in more than 20% of the volcanic

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Maria Teresa Valenti Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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Monica Mottes Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, Verona, Italy

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Samuele Cheri Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy
Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, Verona, Italy

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Michela Deiana Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy
Department of Neurosciences, Biomedicine and Movement Sciences, University of Verona, Verona, Italy

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Valentina Micheletti Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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Elisa Cosaro Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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Maria Vittoria Davì Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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Giuseppe Francia Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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Luca Dalle Carbonare Department of Medicine, Internal Medicine, Section D, University of Verona, Verona, Italy

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13 patients (6 ADPs and 7 TPs). The samples were fixed in 70% ethanol and embedded undecalcified in methyl-methacrylate resin (Merck 800590). Bone sections were cut by using a microtome (Polycut S, Leica Microsystems) equipped with a carbide-tungsten

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